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Mayor Bill de Blasio recently proposed new mandates that would force building owners to make sharp reductions in greenhouse gas emissions. The initiative would mandate that owners of existing buildings larger than 25,000 square feet invest in more efficient heating and cooling systems, insulation, and hot-water heaters in the years ahead. If approved by the City Council, the requirements would apply to about 14,500 private and municipal buildings, which the mayor’s office says collectively account for nearly a quarter of New York City’s emissions.